"I saw cocaine for the first time a month ago in Spain," says Portman, her large, innocent, Audrey Hepburn eyes popping wide open as she curls her tiny body into an armchair. "I mean, for the first time in my life, somebody was like, 'You want a line?' I was like, 'Oh, my God!'" she says, recalling the unbelievable moment. 
Source: Vanity Fair, April 2006
Other fun facts from the article:
-She will not let leather even touch her body.
-Anyone standing next to her looks "out of proportion" because she's so perfectly fucking tiny.
-It was her grandfather's dying wish that she attend Harvard.
-Her professor, Alan Dershowitz, had
no idea she was a Hollywood movie star!