Kate Hudson and Matt Dillon had little to no chemistry in You Me and Dupree. I didn't buy that they were this happily married couple; the chemistry between Kate and Owen was electric, so when Kate and Matt aren't getting along and are on the verge of splitting up, I wasn't rooting for them to get back together ; there was no reason to. I was just waiting for Kate to jump Owens bones the entire time.
And there was ZERO chemistry between Matthew Broderick and Nicole Kidman in Stepword Wives. Hell, that was just painful to watch.
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Gorgeousness & gorgeousity made flesh
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